研究學術成果
解決方案
學術論文：在膨脹型聚丙烯配方中使用聚酰胺-6作為碳化劑 II – 熱降解
Using polyamide 6 as charring agent in intumescent polypropylene formulations II. Thermal degradation
在膨脹型聚丙烯配方中使用聚酰胺-6作為碳化劑 II – 熱降解
作者：Almeras, X., F. Dabrowski, M. Le Bras, R. Delobel, S. Bourbigot, G. Marosi, et P. Anna
發表：Polymer Degradation and Stability 77, no 2 (2002): 315 323. doi:10.1016/S0141-3910(02)00066-6
Abstract/摘要：
The fire performance of intumescent PP/APP/PA6/EVA19 blends were previously put forward in part I of this article. In the present part, the thermal and thermo-oxidative degradations of the formulations are modelled. The comparison between the kinetic data determined in this study and data from previous studies suggests that PP degrades before the reaction between APP and PA6. However it may be supposed that in the conditions of a fire (i.e. at high heating rate) both reactions occur simultaneously. Thus the development of an efficient protective structure is possible which could explain the fire properties of interest observed in the conditions of the cone calorimeter.
Keywords/關鍵詞：
Intumescence 膨脹;
Compatibiliser 協效;
Degradation 降解;
Kinetics 動力學;
Modelling 模化
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